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xenon trioxide : ウィキペディア英語版
xenon trioxide

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Xenon trioxide is an unstable compound of xenon in its +6 oxidation state. It is a very powerful oxidizing agent, and liberates oxygen from water slowly (and xenon), accelerated by exposure to sunlight. It is dangerously explosive upon contact with organic materials. When it detonates, it releases xenon and oxygen gas.
==Chemistry==
Xenon trioxide is a strong oxidising agent and can oxidise most substances that are at all oxidisable. However, it is slow-acting and this reduces its usefulness.
Above 25 °C, xenon trioxide is very prone to violent explosion:
:2 XeO3 → 2 Xe + 3 O2
When it dissolves in water, an acidic solution of xenic acid is formed:
:XeO3 (aq) + H2O → H2XeO4 H+ + HXeO4
This solution is stable at room temperature and lacks the explosive properties of xenon trioxide. It oxidises carboxylic acids quantitatively to carbon dioxide and water.
Alternatively, it dissolves in alkaline solutions to form ''xenates''. The HXeO anion is the predominant species in xenate solutions. These are not stable and begin to disproportionate into perxenates (+8 oxidation state) and xenon and oxygen gas. Solid perxenates containing have been isolated by reacting with an aqueous solution of hydroxides. Xenon trioxide reacts with inorganic fluorides such as KF, RbF, or CsF to form stable solids of the form .

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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